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 UDEL Polysulfone

Chemical Structure

UDEL Structure

Key features

  • Excellent resistance to inorganic acids & bases
  • Withstands repeated exposure to steam sterilization
  • Excellent resistance to hot water
  • Good thermal properties - Heat deflection temperature at 264 psi (1.8 MPa) is 174°C
  • Approved for use with food, water and medical applications

Applications

  • Membranes (hemodialysis, drinking and ultra-pure waters, gas separation, food & beverage concentration, dairy)
  • Medical (surgical trays, nebulizers, humidifiers)
  • Food service (microwave cookware, beverage and food dispensers, milking machine parts)
  • Plumbing (hot water fittings, manifolds, mixer tap cartridges)

UDEL Polysulfone is an amorphous high performance polymer, which is characterized by excellent thermal properties, good resistance to inorganic acids and bases, and outstanding hydrolytic stability against hot water and steam sterilization.
It is toxicologically inert and has extensive regulatory clearance.
In its natural and unmodified form Tg= 190°C; HDT/A= 174°C; RTI= 160°C

Udel® P-1700 NT 11
Udel® P-1800 NT 11   (Powder Version of P-1700) 

UDEL P-1700 LCD  (Low Cyclic Dimer)

UDEL P-1835 NT 11 (Powder Version of P-3500)
UDEL P-3500 LCD MB (Low Cyclic Dimer) 

Cyclic Dimer in UDEL® Polysulfone

For some membrane producers, the level of Cyclic Dimer (CD) can be important to their processing efficiencies and fiber quality.

Too much cyclic dimer can result in:
  • Filtered dope solutions becoming cloudy
  • White solid material clogging the process filters

Standard Grades of UDEL Polysulfone:

  • Contain 1.5% by weight of cyclic dimer
  • In solution and in the presence of non-solvents such as pore-formers, crystallization may occur
  • Even on prolonged aging, only a small amount precipitates.

LCD (Low Cyclic Dimer) Grades of UDEL Polysulfone

  • Contains 1.20% by weight of cyclic dimer
  • Remain clear (reduced precipitation) for a longer period of time than standard grades of UDEL polysulfone.
  • For example, at 40°C, UDEL P-3500 LCD dope solution is 10 times clearer than
    UDEL P-3500 NT 11

The Benefits to Membrane Producers of the LCD Grades are: 

1. Economic, Less precipitation in process equipment (vessels, pumps...) resulting in :

  • Longer shelf-life for dope solutions
  • Longer filter life
  • Fewer shut-downs for cleaning
  • Longer continuous runs

2. Technical, LCD resins have 10% higher Mn (Number Average Molecular Weight) for a given Mw (Weight Average Molecular Weight)

  • Higher fiber strength
  • Fewer fiber breakages
  • Fewer surface defects, and therefore fewer rejects
  • Higher-performing membranes

To read a Technical Paper that appeared in the journal "Desalination" in 2002, Volume 144, discussing cyclic dimer in polysulfone, click here.

 

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Date of last update: 9/3/2010